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Ammonium Nitrate

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Ammonium Nitrate in EutrophicationAmmonium Nitrate in Eutrophication

Ammonium Nitrate, white solid used as a synthetic nitrogen fertilizer. Its formula is NH4NO3. It must be stored carefully as it can explode, and it is consequently used in some explosives.

Ammonium nitrate is manufactured in large quantities from ammonia, produced by the Haber process. Some of the ammonia (NH3) is converted to nitric acid (HNO3) in a three-stage process, using both air and water:

4NH3 + 5O2→4NO + 6H2O



2NO + O2⇋2NO2



4NO2 + 2H2O + O2→4HNO3

Reaction of ammonia with nitric acid then produces ammonium nitrate:

NH3 + HNO3→NH4NO3

Ammonium nitrate is usually made in the form of small granules called prills. These are easy to handle and distribute on farmland.

Ammonium nitrate contains 35 per cent nitrogen. It is readily soluble in water. This makes it quick-acting, but it is quickly washed off fields into water-courses. This can cause water pollution problems because the ammonium nitrate removes dissolved oxygen from the water.

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